Term to describe relationship between one and single, two and double, etc.?

The terms are "Cardinal" and "Ordinal" and "Distributive". One, two, three, etc. are "Cardinal Numbers." First, second, third, etc. are "Ordinal Numbers" (which tell Order). "Distributive Numbers" tell how many of each like Singly,Doubly,Triply and Single,Double,Triple.

We often get the various -nary terms like binary, ternary, and quaternary from Latin distributive numbers (bini, terni, quaterni, quini, seni, etc.), with the exception of unary which comes from their cardinal number one (unus) as opposed to their distributive number one (singuli, which is where singular, single, singularity, etc. come from). Words like primary, secondary, and tertiary usually come from their ordinal numbers (primus, secundus, tertius, quartus, quintus, etc.).

You could say the latter is derivative of the former.