Volatile Struct Semantics

In your example, the two are the same. But the issues revolve around pointers.

First off, volatile uint8_t *foo; tells the compiler the memory being pointed to is volatile. If you want to mark the pointer itself as volatile, you would need to do uint8_t * volatile foo;

And that is where you get to the main differences between marking the struct as volatile vs marking individual fields. If you had:

typedef struct
{
    uint8_t *field;
} foo;

volatile foo f;

That would act like:

typedef struct
{
    uint8_t * volatile field;
} foo;

and not like:

typedef struct
{
    volatile uint8_t *field;
} foo;

if you declare a structure with volatile then all its members will also be volatile