I Would Like To Open Files in Different Tabs in the Same Window Using Xcode 5

Left column in Xcode is called Navigator. You can show/hide it with +0 (Zero), or in the upper right window corner, see image: enter image description here

In the Navigator there are dfferent tabs (Project Navigator, Symbols Navigator etc.). To see list of files in Your project You need to select Project Navigator or press +1.

To open file in current tab, single click on it in Navigator. If You double click the file, it would open in new window/tab. You can change the behaviour of double click in Preferences... -> Navigation -> Double Click Navigation.