/usr/local/bin/python3: No module named pip Error on or near line 85; exiting with status 1

Because you have python3-pip package installed, you need to invoke that as pip3:

pip3 list
sudo pip3 install virtualenv

It means you need to install pip using this commmand-

sudo apt install python3-pip

if python3 is the only version of python installed then pip should invoke pip3 when used.