When should I start seeking out DLC missions?

Dawnguard has a minimum level requirement of 10. I'd recommend waiting until 15-20 though since some of the quests are long and tough (lots of trekking through falmer infested territory).

Hearthfire can be started at any time as its simply a material collection quest to build a house. Though collecting all the materials may take a long time. To get the courier letter, you must be level 10.

Dragonborn requires you to have started the Horn of Jurgen Windcaller quest. This is a tough DLC and having good gear matters more than levels, I wouldn't recommend anything below 30.

To start the Dawnguard main quest (and also the side quests) your character must either be at level 10 or above, or you need to go to Fort Dawnguard. You will get the quest by visiting a city and listening for rumors, someone will approach you to recruit you into the Dawnguard or by going to the fort and speaking with Isran. There is also a side quest (Lost to the Ages) after you read a book (The Aetherium Wars).

For Hearthfire there is no particular quest, just get along with the jarls, buy land for them and built your dream house. And then you can adopt children, decorate your house and so on...

For Dragonborn, you must have at least started the quest The Horn of Jurgen Windcallert to start the main questline. After that, the next time you visit a city two Cultists will engage you in a brief discussion and then will attempt to kill you. Once they're dead, a note can be found on one of them which will trigger the quest.

For DLC quests I believe they are quiet separated from the main story (that's what I think, as I've only Dawnguard DLC atm). The leveling for enemies in DLC will depend on your level and I suggest you to get around level 25-35 before jumping into the main DLC quest.